Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism

Articolo

Data di Pubblicazione:

1995

Citazione:

(1995). Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism [journal article - articolo]. In TETRAHEDRON LETTERS. Retrieved from https://hdl.handle.net/10446/232225

Abstract:

The oxidation of alkanes by dimethyldioxirane (DMD) in the presence of CBrCl3 provides strong evidence that free-radicals are involved in the reaction; enthalpic and polar effects and an "oxygen rebound" mechanism are suggested to explain the exceptional oxidation selectivity.

Tipologia CRIS:

1.1.01 Articoli/Saggi in rivista - Journal Articles/Essays

Elenco autori: